“…Microdroplets, the scale-down analytical platforms, are commonly used in the fields of analytical chemistry [ 1 ], biology [ 2 ], material synthesis [ 3 ], and so on. Understanding the impacting mechanism between a liquid-in-air droplet and an immiscible aqueous solution is important and helpful for lots of applications, such as biofabrication through inkjet printing [ 4 , 5 ] and droplet encapsulation [ 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 ] for drug delivery [ 14 , 15 ], PCR reaction [ 16 , 17 ], and preparation of Janus droplets [ 18 ] or double-emulsions [ 19 , 20 ]. When the oil droplet impacts with another immiscible aqueous solution, it will transiently knock a crater on the surface of the aqueous solution and lead to the floating, bouncing, jetting, or splashing of the solution [ 21 , 22 , 23 ].…”