2006
DOI: 10.1007/s00216-006-0521-3
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Analysis of nitrated polycyclic aromatic hydrocarbons

Abstract: Many nitrated polycyclic aromatic hydrocarbons (NPAH) that are present in low concentrations in the environment and in emission sources have been shown to be mutagenic and/or carcinogenic. This paper reviews the current methods of analysis of these compounds with the emphasis on NPAH measurements in ambient particulate matter samples.

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Cited by 56 publications
(51 citation statements)
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“…Of most interest are nitrogen-substituted derivatives (NPAHs), oxygenated PAHs (OPAHs), methylated PAHs (MPAHs), and amino PAHs (APAHs). NPAHs form during the combustion cycle as a result of reactions with either HNO 3 or NO x and have been described previously (Sienra and Rosazza 2006;Zielinska and Samy 2006;Delhomme et al 2007;Hattori et al 2007). OPAHs may include carboxylate, hydroxy, dihydroxy, aldehyde, carboxaldehyde, ketone, and acetoxy functional groups and can be divided into two subgroups; carboxylated PAHs that contain one or more carbonyl oxygen(s) attached to the aromatic ring (ketones and quinones) and hydroxylated PAHs containing one or more hydroxyl groups.…”
Section: Introductionmentioning
confidence: 83%
“…Of most interest are nitrogen-substituted derivatives (NPAHs), oxygenated PAHs (OPAHs), methylated PAHs (MPAHs), and amino PAHs (APAHs). NPAHs form during the combustion cycle as a result of reactions with either HNO 3 or NO x and have been described previously (Sienra and Rosazza 2006;Zielinska and Samy 2006;Delhomme et al 2007;Hattori et al 2007). OPAHs may include carboxylate, hydroxy, dihydroxy, aldehyde, carboxaldehyde, ketone, and acetoxy functional groups and can be divided into two subgroups; carboxylated PAHs that contain one or more carbonyl oxygen(s) attached to the aromatic ring (ketones and quinones) and hydroxylated PAHs containing one or more hydroxyl groups.…”
Section: Introductionmentioning
confidence: 83%
“…filter) samples of aerosols, and their unique advances are in the area of molecular characterisation of organic aerosols. [23][24][25][26][27][28] Online techniques employ rapid sampling of particles followed by evaporation and ionisation of the resulting vapour. [29][30][31][32][33][34][35][36] Critical advantages of the online techniques are simultaneous measurements of particle composition, as well as size, high temporal resolution, and ability to distinguish between internally and externally mixed particle components.…”
Section: Alexander Laskin Is a Senior Research Scientist At Pacific Nmentioning
confidence: 99%
“…11; PAHs may also be released via agricultural fires and cooking. The researchers have found out the characteristics of the precursor sources (i.e., whether they are pyrogenic or petrogenic) through the PAHs distributed in the sediments (Aboul-Kassim & Simueit, 1995;ATSDR, 1995;Zielinska & Samy, 2006).…”
Section: Polycyclic Aromatic Hydrocarbons (Pahs)mentioning
confidence: 99%