2022
DOI: 10.1007/s10553-022-01429-w
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Analysis of the Techniques for Measuring the Equilibrium Conditions of Gas Hydrates Formation

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Cited by 12 publications
(5 citation statements)
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“…The original research paper describes ramp and step heating techniques for hydrate equilibrium measurements [1] . Their applicability to different systems is analyzed in our recent work [20] . Figs.…”
Section: Experimental Design Materials and Methodsmentioning
confidence: 99%
“…The original research paper describes ramp and step heating techniques for hydrate equilibrium measurements [1] . Their applicability to different systems is analyzed in our recent work [20] . Figs.…”
Section: Experimental Design Materials and Methodsmentioning
confidence: 99%
“…Air was removed from the free volume of the vessel by flushing with gaseous methane three times (we estimate the residual air content in the gas phase at 0.001–0.002 vol%). The three-phase gas–aqueous solution–hydrate equilibrium in the CH 4 –H 2 O–THI system was measured by the method described earlier [ 12 , 13 ]. Pressure and temperature of complete dissociation of methane hydrate at slow ramp heating (0.1 K/h) and simultaneous vigorous mixing of fluids (600 rpm) were taken as coordinates of the equilibrium point .…”
Section: Experimental Design Materials and Methodsmentioning
confidence: 99%
“…The empty space of the vessel was purged thrice with gaseous methane. Measurements of hydrate equilibria were performed according to the technique previously analyzed in detail [6] . The validity of this technique has been confirmed for various systems with thermodynamic inhibitors such as DMSO [ 7 , 8 ], urea [9] , methanol [ 10 , 11 ], and glycols [12] .…”
Section: Experimental Design Materials and Methodsmentioning
confidence: 99%