Anchoring Catalytic Metal Nodes within a Single‐Crystalline Pyrazolate Metal‐Organic Framework for Efficient Heterogeneous Catalysis
Rong‐Ran Liang,
Zhaoyi Liu,
Zongsu Han
et al.
Abstract:The synthesis of single‐crystalline and robust pyrazolate metal‐organic frameworks (Pz‐MOFs) capable of facilitating challenging organic transformations is fundamentally significant in catalysis. Here we demonstrate a metal‐node‐based catalytic site anchoring strategy by synthesizing a single‐crystalline and robust Pz‐MOF (PCN‐1004). PCN‐1004 features one‐dimensional (1D) copper‐Pz chains interconnected by well‐organized ligands, forming a porous three‐dimensional (3D) network with two types of 1D open channel… Show more
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