And Contain Cobalt

Abrahamson, Harmon B.

doi:10.1002/9780470145302.ch95

Inorganic Reactions and Methods

1986

DOI: 10.1002/9780470145302.ch95

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And Contain Cobalt

Harmon B. Abrahamson¹

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2022

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Cobalt‐Catalyzed Deaminative Amino‐ and Alkoxycarbonylation of Aryl Trialkylammonium Salts Promoted by Visible Light

2022

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Catalytic carbonylations of aryl electrophiles via C(sp 2 )À N cleavage remains a significant challenge. Herein, we demonstrate an aminocarbonylation of aniline-derived trialkylammonium salts promoted by visible light with a simple cobalt catalyst. The reaction proceeds under mild conditions suitable for late-stage functionalization and is amenable to telescoped carbonylations directly from anilines. A range of alkylamines are successful partners, and alkoxycarbonylation is also demonstrated. Mechanistic studies and DFT calculations support a novel mechanism for catalytic carbonylations of aryl electrophiles involving a key visible light-induced carbonyl photodissociation.

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Cobalt‐Catalyzed Deaminative Amino‐ and Alkoxycarbonylation of Aryl Trialkylammonium Salts Promoted by Visible Light

2022

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Cobalt‐Catalyzed Deaminative Amino‐ and Alkoxycarbonylation of Aryl Trialkylammonium Salts Promoted by Visible Light

2022

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And Contain Cobalt

Cited by 2 publications

References 13 publications

Cobalt‐Catalyzed Deaminative Amino‐ and Alkoxycarbonylation of Aryl Trialkylammonium Salts Promoted by Visible Light

Cobalt‐Catalyzed Deaminative Amino‐ and Alkoxycarbonylation of Aryl Trialkylammonium Salts Promoted by Visible Light

Cobalt‐Catalyzed Deaminative Amino‐ and Alkoxycarbonylation of Aryl Trialkylammonium Salts Promoted by Visible Light

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