1999
DOI: 10.1149/1.1392610
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Anion and Solvent Exchange as a Function of the Redox States in Polyaniline Films

Abstract: Intensive improvements in electroactive polymer research has provided a wide range of new materials with notable technological uses. Considerable interest has been displayed in the development of modified electrodes with electrochemically reactive polymeric materials due to their potential application in energy storage, electrochromic devices, chemical sensors, and a series of other electrochemical devices. 1,2 Novel techniques, such as the electrochemical quartz crystal microbalance (EQCM), 3-9 radio tracer m… Show more

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Cited by 49 publications
(10 citation statements)
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“…In order to check the ions fluxes in PANI/SPANI/rGO films, the plots of number of moles of the exchanged protons g H + and anions g A À vs. the potential were obtained by using the following equations [38][39][40]: …”
Section: Electrochemical Performance Of Pani/spani/rgo Composite Filmmentioning
confidence: 99%
“…In order to check the ions fluxes in PANI/SPANI/rGO films, the plots of number of moles of the exchanged protons g H + and anions g A À vs. the potential were obtained by using the following equations [38][39][40]: …”
Section: Electrochemical Performance Of Pani/spani/rgo Composite Filmmentioning
confidence: 99%
“…When the species (anions and/or solvent and/or cation) pass in and out of polymer matrix, the mass changes of poly(PD-BCD) films (Dm) could be expressed by the following equation [1,22]:…”
Section: Article In Pressmentioning
confidence: 99%
“…EQCM technique can be a convenient method to analyze in situ ion transport within a polymer film during electrochemical cycling. The transports of cations, anions, and solvent, coming either from the bulk electrolyte or the polymer film, result in the measured mass changes [18], and the mass balance can be written as…”
Section: Ion Transport Phenomenamentioning
confidence: 99%