In this paper, we develop two anisotropic solutions for static selfgravitating spherical structure in the presence of electromagnetic field through gravitational decoupling approach in f (G, T ) theory, where G and T denote the Gauss-Bonnet term and trace of the energymomentum tensor, respectively. The extra source with isotropic seed sector is responsible for generating anisotropy in the spacetime. The system of field equations is decoupled into two arrays by using minimal geometric deformation in the radial component. The first set portrays the isotropic regime whereas the second set represents the anisotropic system. The metric coefficients of the Krori-Barua spacetime are employed to extract solution of the first set while two constraints on the radial and temporal components of the extra source yield the corresponding two solutions. Finally, we investigate the influence of charge and decoupling parameter on the physical viability and stability of the obtained solutions. We conclude that the resulting solutions in this modified theory indicate more feasible and stable structures.