We study the occurrence of ground-state factorization in dimerized XY spin chains in a transverse field. Together with the usual ferromagnetic and antiferromagnetic regimes, a third case emerges, with no analogous in translationally invariant systems, consisting of an antiferromagnetic Neél-type ground state where pairs of spins represent the unitary cell. Then, we calculate the exact solution of the model and show that the factorizing field represent an accidental degeneracy point of the Hamiltonian. Finally, we extend the study of the existence of ground-state factorization to a more general class of models. The study of zero-temperature critical phenomena in quantum magnetic systems represents since long time a major research subject. [1][2][3][4] In particular, the XY model is a very rich source of information about the quantum behavior of spin chains because of the availability of an exact analytical solution.3,5 During the last years, the main interest about spin chains concerned the relationship between quantum phase transitions and entanglement. 6-9 Among a number of interesting properties of such systems, it is worth citing the existence of special values of the external magnetic field, the parameter which drives the phase transition, which give rise to ground-state factorization, discovered by Kurmann et al. 10 This phenomenon has been observed in two-dimensional lattices through quantum Monte Carlo methods 11 and fully analyzed by Giampaolo et al. 12 in a recent publication, where the factorizing field has been determined for a quite general class of models. They developed an appropriate measure of entanglement which vanishes at the factorizing point. So far, the existence of a factorized ground state has been predicted only in translationally invariant Hamiltonian models.Moreover, critical properties of physical systems are discussed by taking the thermodynamic limit from the beginning. On the other hand, the knowledge of a finite-size solution clarifies important aspects of this limit. For example, it is known that the quantum phase diagram of the XY chain in a transverse field exhibits two different symmetry-broken regions characterized by different behaviors of two-body correlation functions. This dissimilarity has a microscopic origin easily understood in the finite-size case. Besides these considerations, the study of finite systems is relevant by itself for the realization of mesoscopic qubits of contemporary interest.In this Rapid Communication we discuss a finite-size dimerized XY spin chain in a transverse field, and analyze ground-state properties. The interest about such a system, belonging to a more general class of models, 13-15 is motivated by experimental work on quasicrystals and quasiperiodic superlattices. 16,17 First of all, we show that the model admits the existence of a factorized ground state, and then we discuss the exact solution. The factorizing field turns out to be an accidental degeneracy point of the Hamiltonian and falls on a border surface between two regions tha...