In the NMSSM, because of introducing a complex singlet superfield, the lightest CP-odd Higgs boson, a 1 , can be a singlet-like state with a tiny doublet component in large regions of parameter space. In this paper, we examine the discovery potential of a 1 produced in association with a bottom-antibottom pair at the LHC through τ + τ − and γγ decay modes. It is shown that an a 1 with mass ≤ M Z can be extracted from the SM backgrounds by using the τ + τ − decay channel, a possibility precluded to the MSSM. In contrast, the γγ decay mode is overwhelmed by backgrounds despite the fact that the branching ratio of this mode can reach unity when a 1 is a pure singlet.