The continuous monitoring systems developed for health and safety provisions in underground mines have always been a deep concern in mining activity, since this is one of the most dangerous work activities in the world. All mining activities must follow strict regulations that pose an increased responsibility for the design and implementation of novel technologies aiming to enhance both the workers’ and equipment’s safety in underground mines. Coal mines are some of the most dangerous, with high risk of explosion due to pit gas; therefore, we propose the use of visible light communication for local wireless transmission and optical fiber for remote-cabled transmission. We address, in this article, a complete system comprising real-time personnel tracking and environmental methane measurement, as well as the transmission of data, with a detailed explanation of the complete system and technical description with practical solutions applicable for industrial use.