“…includes several representative examples of the reported MOF-based coatings for this SPME geometry together with other configurations [48][49][50][51][61][62][63][64][65][66][67][68][69][70][71][72][73][74][75][76]. The vast majority of reported MOF-based f-SPME devices uses the most common MOFs, such as: HKUST-1-composed of copper nodes and 1,3,5-benzenetricarboxylate struts [61,65,[77][78][79]; UiO-66-formed by the combination of Zr clusters and 1,4-benzenedicarboxylate ligands [62,67,80,81]; MIL-type MOFs, synthesized using 1,4-benzenedicarboxylate ligands and different metal ions, including Cr [68,69,82,83], Fe [84][85][86][87], and Al [66,88]; and MOFs composed of Zn metal centers, including MOF-5 with 1,4-benzenedicarboxylate as ligand [64,[89][90][91][92], and the family of ZIF MOFs containing imidazolate-based ligands ...…”