Arsenic Analysis in the Petroleum Industry: A Review

Abstract

The presence of arsenic in natural gas and liquid hydrocarbons is of great concern for oil companies. In addition to health risks due to its toxicity as well as environmental issues, arsenic is responsible for irreversible poisoning of catalysts and clogging of pipes via the accumulation of As-containing precipitates. To address these problems and to better design treatment units, robust methods for the analysis of arsenic and its compounds in oil streams are required. In addition, the use of feedstocks as a novel source of energy is becoming increasingly important. Most biomasses used as feedstocks are contaminated with arsenic. To avoid problems related to the presence of this element, it is therefore also necessary to have reliable methods for the analysis of arsenic and its compounds in these new fluids. This review outlines the sampling techniques, sample preparation methods, and arsenic analysis techniques developed during recent decades and commonly used in the oil industry and in the new feedstock energy domain.

Atomic spectrometry update: review of advances in the analysis of metals, chemicals and materials

“…The last paper in this section is a review article by Mere et al containing 52 references on arsenic determination in the petroleum industry . 98 The presence of As in natural gas and liquid hydrocarbons is of great concern for oil companies. In addition to health risks due to its toxicity and environmental issues As is responsible for irreversible poisoning of catalysts and clogging of pipes via the accumulation of As-containing precipitates.…”

Synergistic effect of arsenic removal from petroleum condensate via liquid-liquid extraction: Thermodynamics, kinetics, DFT and McCabe-Thiele method

“…Upstream condensates contain an over-limiting concentration of arsenic. In general, various forms of arsenic contaminated in condensates can be found: namely, trimethylarsine or TMA ((CH 3 ) 3 As), triethylarsine ((C 2 H 5 ) 3 As), triphenylarsine ((C 6 H 5 ) 3 As), and arsine (AsH 3 ) in the range of 0.04–514 mg/L depending on the oil and gas wells [ 3 , 4 ]. Arsenic is a highly poisonous metal and can cause chronic and acute poisoning in humans [ 5 ].…”