This review presents a detailed analysis of hydrogeological and hydrochemical conditions of the Niger Delta Basin. Hydrogeologically, the specific capacities recorded from different areas within this Basin vary from 6700 lit/hr/m to 13,500 lit/ hr/m. The water table is very close to the ground surface and varies from 0 to 4 meters. Unconfined groundwater aquifers occur in shallow unconfined aquifers, sands of the coastal beach ridges and river point bars, and sandy islands within the mangrove belt. There is a stable water table fluctuation which characterised the high precipitation zone. The shallow aquifers of Benin Formation are more porous than those in the Deltaic areas. In the southern areas, along the coastal zone, an artesian condition occurs. However, the aquifers are less transmissible with increased depth of the confined aquifer, owing to its more delicate texture. Therefore, more compact, and less permeable, or that there is not enough water in storage. More than half of groundwater sources in the Basin are acidic. Based on mean TDS concentration groundwater, fall in an excellent class for drinking. Groundwater classification based on conductivity showed all the reported findings indicate conductivity ranging from 250-750 μS/cm. Based on cation and anion chemistry, the Niger Delta Basin holds water of relatively acceptable drinking quality. However, the uncontrolled groundwater development, land-use changes, pollution from industrial, municipal, and agricultural effluents pose a threat to groundwater quality protection. Thus, a policy guideline is required to protect groundwater from pollution.