Atom transfer radical copolymerization of methyl methacrylate withN-cyclohexylmaleimide

Jiang, Xulin; Yan, Deyue; Zhong, Yalan; Liu, Wanli; Chen, Qingxiang

doi:10.1002/1097-0126(200008)49:8<893::aid-pi516>3.0.co;2-a

Cited by 9 publications

(6 citation statements)

References 29 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…264 The R-Cl/CuCl system also gave R-13 although the MWDs became slightly broader (M w /M n ) 1.3-1.4). 366 Other methacrylate-based copolymers are also possible with acrylamide (R-14) 370 and maleimide (R-15), 410 which can be prepared by ruthenium and copper catalysts, respectively. Both copolymers have amide groups randomly distributed in the PMMA chains.…”

Section: Random Copolymersmentioning

confidence: 99%

Metal-Catalyzed Living Radical Polymerization

2001

View full text Add to dashboard Cite

Section: Random Copolymersmentioning

confidence: 99%

Metal-Catalyzed Living Radical Polymerization

2001

View full text Add to dashboard Cite

“…The T g values are given in Table 2. The T g values of PS and PMMA were taken as 100 and 105 °C, respectively, from literature data 23, 30, 31. The T g of P‐1 was obtained as T g = 113 °C.…”

Section: Resultsmentioning

confidence: 99%

Synthesis and characterization of novel poly(cycloalkyl methacrylate) bearing fused‐ring structure and its copolymers

Asha

Deepthimol

Lekshmi

2004

J. Polym. Sci. A Polym. Chem.

View full text Add to dashboard Cite

A new family of cycloaliphatic fused‐ring acrylic polymers based on 8‐hydroxymethyltricyclo[5.2.1.02,6]decane (TCD) has been synthesized by free‐radical polymerization. TCD‐methacrylate (TCD‐MA) was synthesized by reacting TCD with methacrylic acid in toluene via transesterification with p‐toluenesulfonic acid as a catalyst. TCDMA was polymerized in toluene with benzoyl peroxide as a free‐radical initiator at 80 °C. Copolymers were synthesized by polymerizing TCDMA with styrene and methyl methacrylate. The composition of the comonomers was varied from 0 to 100%. Homo‐ and copolymers were characterized by Fourier transform infrared (FTIR) and 13C NMR spectroscopy. Molecular weight determination by gel permeation chromatography showed that the polymers were obtained in very high molecular weights in the range of Mn > 50,000 and Mw > 80,000 with relatively low polydispersity. The composition analysis of both the copolymer series were determined by 1H NMR. The thermal properties of the homo‐ and copolymers were studied with differential scanning calorimetry and all the polymers were found to be amorphous. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5617–5626, 2004

show abstract

“…It should be noted that there is an obvious positive intercept in the pseudo-rst order kinetic plot, especially temperature is 80 C. This may result from the thermal initiation of the co-monomers at higher temperature. 19 Fig. 1(B) shows the evolution of M n,GPC and M w /M n versus monomer conversion.…”

Section: Kinetics Of Raft Copolymerizationmentioning

confidence: 99%