2023
DOI: 10.1039/d2ta08566f
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Atomic-level orbital coupling in a tri-metal alloy site enables highly efficient reversible oxygen electrocatalysis

Abstract: Complex multi-metallic alloys with ultra-small sizes have received extensive attention in the fields of Zn-air battery and water splitting, because of their unique advantages including adjustable composition, tailorable active site,...

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Cited by 37 publications
(16 citation statements)
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“…The Ni 2p 3/2 spectrum is decomposed as described in literature [86,87] . In the spent Sg OxMix sample, additional features at a binding energy of 852.2 [86,88] eV and spin‐orbit of 17 eV are attributed to Ni 0 formation at the surface with strong metal‐support interactions, [89] quantified as 20 % of the Ni 2p 3/2 peak (See Table 6).…”
Section: Resultsmentioning
confidence: 99%
“…The Ni 2p 3/2 spectrum is decomposed as described in literature [86,87] . In the spent Sg OxMix sample, additional features at a binding energy of 852.2 [86,88] eV and spin‐orbit of 17 eV are attributed to Ni 0 formation at the surface with strong metal‐support interactions, [89] quantified as 20 % of the Ni 2p 3/2 peak (See Table 6).…”
Section: Resultsmentioning
confidence: 99%
“…The electron transfer number (n) involved in the process of the ORR was quantified using the rotating ring-disk electrode, resulting in a calculated n value of approximately 4 for the Fe-Co/ Mo 2 C@NCF. 55,56 The yield of peroxide species also proves negligible, as deduced from eqn (1) and ( 2). This observation suggests that the Fe-Co/Mo 2 C@NCF catalyst can effectively initiate the ORR process via a desirable and evident four-electron mechanism, highlighting its potential as an exceptionally efficient catalyst for the ORR, as illustrated in Fig.…”
Section: Evaluation Of Orr Performancementioning
confidence: 88%
“…In the sports field, human motion monitoring enables the evaluation of athletes’ performance and physical fitness, while in the medical field, it plays a crucial role in diagnosing and guiding patients’ physical rehabilitation. , For instance, monitoring heart rate and running stride allows for customized adjustments to athlete running details, while monitoring a patient’s pulse and limb bending ability enables an assessment of their condition. Recently, the application of wearable motion sensors has received extensive attention due to their flexibility, accuracy, and real-time reminders. However, most of these electronic devices are comprised of rigid materials (e.g., metals, inorganic semiconductors, and carbon materials, etc.). This strategy provided excellent reliability and conductivity but caused a mechanical strength mismatch at the device/skin interface and wearing discomfort.…”
Section: Introductionmentioning
confidence: 99%