The development of oxygen evolution reaction (OER) electrocatalysts is essential for the production of green hydrogen from water electrolysis, but it is challenging. Herein, ruthenium (Ru) single-atommodified Co-HHTP (HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene) (Ru@Co-HHTP) was prepared via a solvothermal and ion exchange method. Systematic experiments highlight that the atomically dispersed Ru can optimize the electronic structure and electronic conductivity of Co-HHTP. As a result, the obtained Ru@Co-HHTP shows a low overpotential of 247 mV at 100 mA cm −2 , a small Tafel slope of 38.14 mV dec −1 , and good stability, which are superior to those of Co-HHTP, commercial IrO 2 , and most previously reported catalysts. This work provides a new avenue for designing highly efficient elongated OER electrocatalysts.