Chem. Sci.
 2024
DOI: 10.1039/d4sc01913j
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BP double bonds relieved from steric encumbrance: matrix-isolation infrared spectroscopy of the phosphaborene F2B–PBF and the triradical BPF3

Mei Wen,
Robert Medel,
Pavel V. Zasimov
et al.

Abstract: Free phosphaborenes have a labile boron-phosphorus double bond and therefore require extensive steric shielding by bulky substituents to prevent isomerisation and oligomerisation. In the present work, the small free phosphaborene...

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