“…Perovskites with general formula ABO 3 are an important family of multifunctional materials [1] and exhibit a broad variety of outstanding properties, which are widely used in various technological applications such as Solid Oxide Fuel Cells (SOFC) [2,3], steam electrolysis [4], substrates for multiferroic materials [5,6], piezoelectricity [7][8][9][10][11][12][13] or catalysis [14][15][16]. Among different perovskite compounds, barium zirconate BaZrO 3 (BZO) has attracted renewed interests as a high-temperature proton conductor [17], a dielectric material for wireless communication applications [18], a substrate for thin-film growth [19,20] and as an inert crucible for superconductors crystal growth [21]. Owing to its large lattice constant, high melting point, low thermal expansion coefficient, low dielectric loss, and low thermal conductivity [22][23][24], BaZrO 3 has become popular for both fundamental research and device applications.…”