Abstract:The crystal of the title compound [systematic name: 4-(benzylamino)benzenesulfonamide], C13H14N2O2S, displays a hydrogen-bonded framework structure. Molecules are doubly N—H⋯O hydrogen bonded to one another via their NH2 groups and sulfonyl O atoms. These interactions generate a hydrogen-bonded ladder structure parallel to the a axis, which contains fused R
2
2(8) rings. The NH group serves as the hydrogen-bond donor for a second set of intermolecular N—H⋯O=S interactions.
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