Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks

Martin, Corey R.; Leith, Gabrielle A.; Shustova, Natalia B.

doi:10.1039/d1sc01827b

Cited by 48 publications

(41 citation statements)

References 290 publications

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“…), in MOFs, the anionic species is replaced by an organic linker [ 6 ]. It should be noted that MOF nodes with unique elements from across the periodic table have also been synthesized [ 11 , 12 , 13 ]. This variation in nodes typically impacts analyte affinity to induce electrostatic interactions as well as the thermal and chemical stability of the MOF.…”

Section: Metal–organic Framework: Synthesis Structure and Propertiesmentioning

confidence: 99%

The Surge of Metal–Organic-Framework (MOFs)-Based Electrodes as Key Elements in Electrochemically Driven Processes for the Environment

et al. 2021

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Metal–organic-frameworks (MOFs) are emerging materials used in the environmental electrochemistry community for Faradaic and non-Faradaic water remediation technologies. It has been concluded that MOF-based materials show improvement in performance compared to traditional (non-)faradaic materials. In particular, this review outlines MOF synthesis and their application in the fields of electron- and photoelectron-Fenton degradation reactions, photoelectrocatalytic degradations, and capacitive deionization physical separations. This work overviews the main electrode materials used for the different environmental remediation processes, discusses the main performance enhancements achieved via the utilization of MOFs compared to traditional materials, and provides perspective and insights for the further development of the utilization of MOF-derived materials in electrified water treatment.

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Section: Metal–organic Framework: Synthesis Structure and Propertiesmentioning

confidence: 99%

The Surge of Metal–Organic-Framework (MOFs)-Based Electrodes as Key Elements in Electrochemically Driven Processes for the Environment

et al. 2021

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“…Elucidation of the chemical bonding in lanthanide (Ln) and actinide (An) systems is presently the goal of many joint experimental and theoretical efforts. Such knowledge is of paramount importance for a wide range of applications, including the development of Ln and An-based single-molecule magnets, [1][2][3][4][5][6] metal-organic frameworks, [7][8][9][10][11] endohedral metallofullerenes, [12][13][14][15][16][17] nanoparticles for industrial catalytic reactions and biomedicine, 18 and the design of chelating ligands for f-element separation. [19][20][21][22][23] Rational design of new f-element materials and separation ligands requires knowledge of the ionic vs. covalent behavior of the Ln 4f/5f and An 5f/6d shells.…”

Section: Introductionmentioning

confidence: 99%

Covalency in actinide(iv) hexachlorides in relation to the chlorine K-edge X-ray absorption structure

Sergentu

Autschbach

2022

Chem. Sci.

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“…Due to their toxicity and reactivity, expensive safety measures are required to handle, store, and transport these gases safely, thereby placing their usage in synthetic chemistry under strict regulations [7] . Herein, we probed metal‐organic frameworks (MOFs), [8–33] specifically their reversible gas adsorption and catalytic activity, to carry out chemical reactions in organic solvents. Thus, we explored the dual role of MOFs as a catalyst and carrier of reagents on the example of reactive gases.…”

Section: Introductionmentioning

confidence: 99%

A Metal‐Organic Framework (MOF)‐Based Multifunctional Cargo Vehicle for Reactive‐Gas Delivery and Catalysis

et al. 2022

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The efficient delivery of reactive and toxic gaseous reagents to organic reactions was studied using metal‐organic frameworks (MOFs). The simultaneous cargo vehicle and catalytic capabilities of several MOFs were probed for the first time using the examples of aromatization, aminocarbonylation, and carbonylative Suzuki–Miyaura coupling reactions. These reactions highlight that MOFs can serve a dual role as a gas cargo vehicle and a catalyst, leading to product formation with yields similar to reactions employing pure gases. Furthermore, the MOFs can be recycled without sacrificing product yield, while simultaneously maintaining crystallinity. The reported findings were supported crystallographically and spectroscopically (e.g., diffuse reflectance infrared Fourier transform spectroscopy), foreshadowing a pathway for the development of multifunctional MOF‐based reagent‐catalyst cargo vessels for reactive gas reagents as an attractive alternative to the use of toxic pure gases or gas generators.

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Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks

Abstract: In this perspective, we feature recent advances in the field of actinide-containing metal-organic frameworks (An-MOFs) with a main focus on their electronic, catalytic, photophysical, and sorption properties. This discussion deviates...

Cited by 48 publications

References 290 publications

The Surge of Metal–Organic-Framework (MOFs)-Based Electrodes as Key Elements in Electrochemically Driven Processes for the Environment

The Surge of Metal–Organic-Framework (MOFs)-Based Electrodes as Key Elements in Electrochemically Driven Processes for the Environment

Covalency in actinide(iv) hexachlorides in relation to the chlorine K-edge X-ray absorption structure

A Metal‐Organic Framework (MOF)‐Based Multifunctional Cargo Vehicle for Reactive‐Gas Delivery and Catalysis

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