Bioplastic Nanocomposite Prepared from Acrylated Epoxidized Soybean Oil-PMMA Copolymer and Nano-Titanium Dioxide

Saithai, Pimchanok; Tanrattanakul, Varapon; Dubreucq, Éric; Lecomte, Jérôme

doi:10.1166/asl.2013.4811

Cited by 5 publications

(5 citation statements)

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“…In Figure 3 A, the signal at 5.3 ppm (peak g) corresponds to the unsaturated double bond (C=C) that is present in MO. According to Sathai et al, [ 31 ], an unsaturated double bond signal can be seen at 5.2–5.41 ppm whereas signals for the long chain aliphatic (CH 2 ) and terminal CH 3 would appear at 1.2–1.4 (peak b) and 0.8–0.9 ppm (peak a), respectively. During the epoxidation process, the double bond (C=C) in MO was converted to an epoxide ring (C-O-C) in EMO.…”

Section: Resultsmentioning

confidence: 99%

Optimisation of Epoxide Ring-Opening Reaction for the Synthesis of Bio-Polyol from Palm Oil Derivative Using Response Surface Methodology

Kamairudin¹,

Hoong

Abdullah

et al. 2021

Molecules

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The development of bio-polyol from vegetable oil and its derivatives is gaining much interest from polyurethane industries and academia. In view of this, the availability of methyl oleate derived from palm oil, which is aimed at biodiesel production, provides an excellent feedstock to produce bio-polyol for polyurethane applications. In this recent study, response surface methodology (RSM) with a combination of central composite rotatable design (CCRD) was used to optimise the reaction parameters in order to obtain a maximised hydroxyl value (OHV). Three reaction parameters were selected, namely the mole ratio of epoxidised methyl oleate (EMO) to glycerol (1:5–1:10), the amount of catalyst loading (0.15–0.55%) and reaction temperature (90–150 °C) on a response variable as the hydroxyl value (OHV). The analysis of variance (ANOVA) indicated that the quadratic model was significant at 98% confidence level with (p-value > 0.0001) with an insignificant lack of fit and the regression coefficient (R2) was 0.9897. The optimum reaction conditions established by the predicted model were: 1:10 mole ratio of EMO to glycerol, 0.18% of catalyst and 120 °C reaction temperature, giving a hydroxyl value (OHV) of 306.190 mg KOH/g for the experimental value and 301.248 mg KOH/g for the predicted value. This result proves that the RSM model is capable of forecasting the relevant response. FTIR analysis was employed to monitor the changes of functional group for each synthesis and the confirmation of this finding was analysed by NMR analysis. The viscosity and average molecular weight (MW) were 513.48 mPa and 491 Da, respectively.

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Section: Resultsmentioning

confidence: 99%

Optimisation of Epoxide Ring-Opening Reaction for the Synthesis of Bio-Polyol from Palm Oil Derivative Using Response Surface Methodology

Kamairudin¹,

Hoong

Abdullah

et al. 2021

Molecules

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“…oil (AESO) AESO was prepared from a reaction between ESO and acrylic acid in a similar way to previous reports [39,40]. About 50 g of ESO were placed in a 250 mL round-bottom flask equipped with a magnetic stirrer and a reflux condenser.…”

Section: Synthesis Of Acrylated Epoxidized Soybeanmentioning

confidence: 99%

“…It has been established that AESO shows higher mechanical properties than ESO [22,39]. AESO has been used for copolymerization with other materials such as a vinyl ester resin containing styrene [8][9][10] and with poly(methyl methacrylate) [38][39][40]. It was found that the mechanical properties of an AESO-co-PMMA copolymer were higher than those of AESO.…”

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confidence: 99%

Effects of different epoxidation methods of soybean oil on the characteristics of acrylated epoxidized soybean oil-co-poly(methyl methacrylate) copolymer

Saithai¹,

Lecomte²,

Dubreucq³

et al. 2013

Express Polym. Lett.

124

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“…With respect to the radical polymerization, since the double bonds in most of the oils are nonconjugated which are inactive for radical polymerization, their reactivity can be chemically improved by conjugating the double bonds or converting double bonds into more active groups, such as epoxy [8,9]. The epoxidized plant oils can be chemically produced from plant oil by in-situ epoxidation with hydrogen peroxide and acetic acid in the presence of sulfuric acid as catalyst [10][11][12]. The conversion of double bonds into epoxide groups increases the reactivity of oils due to the ring strain in the epoxy group.…”

Section: Introductionmentioning

confidence: 99%

The reactivity of linseed and soybean oil with different epoxidation degree towards vinyl acetate and impact of the resulting copolymer on the wood durability

Jebrane¹,

Cai²,

Sandström³

et al. 2017

Express Polym. Lett.

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Abstract. Linseed (LO) and soybean oil (SO) were in-situ epoxidized with peracetic acid to produce different degree of epoxidized LO and epoxidized SO. For comparison purpose, commercial epoxidized linseed oil (ELO ® ) and epoxidized soybean oil (ESO ® ) were also included in the study. The effect of epoxidation degree on the copolymerization reaction between epoxidized oils and vinyl acetate (VAc) was investigated. Results showed that a copolymer can be formed between VAc and epoxidized LO with high epoxy content, while no reaction occurred between VAc and SO or its epoxidized derivatives. As the most reactive monomer among the studied oils, the epoxidized LO with highest epoxy content (i.e. ELO ® ) was mixed with VAc and then impregnated into the wood using three different ELO ® /VAc formulations either as solution or as emulsions. After curing, the impact of the resulting copolymer issued from the three tested formulations on the wood durability was evaluated. Results showed that the formulation comprising VAc, ELO ® , H 2 O, K 2 S 2 O 8 and alkaline emulsifier (Formulation 3) can significantly improve wood's durability against white rot-(Trametes versicolor) and brown rot fungi (Postia placenta and Coniophora puteana). Treated wood of 8% weight percentage gain (WPG) was sufficient to ensure decay resistance against the test fungi with less than 5% mass loss.

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Bioplastic Nanocomposite Prepared from Acrylated Epoxidized Soybean Oil-PMMA Copolymer and Nano-Titanium Dioxide

Cited by 5 publications

References 0 publications

Optimisation of Epoxide Ring-Opening Reaction for the Synthesis of Bio-Polyol from Palm Oil Derivative Using Response Surface Methodology

Optimisation of Epoxide Ring-Opening Reaction for the Synthesis of Bio-Polyol from Palm Oil Derivative Using Response Surface Methodology

Effects of different epoxidation methods of soybean oil on the characteristics of acrylated epoxidized soybean oil-co-poly(methyl methacrylate) copolymer

The reactivity of linseed and soybean oil with different epoxidation degree towards vinyl acetate and impact of the resulting copolymer on the wood durability

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