Biorenewable polyethylene terephthalate mimics derived from lignin and acetic acid

Mialon, Laurent; Pemba, Alexander G.; Miller, Stephen A.

doi:10.1039/c0gc00150c

Cited by 205 publications

(173 citation statements)

References 14 publications

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“…Bio-based polymers using ferulic acid have been reported, including polyester (Mialon et al 2010;Kreye et al 2013;Pion et al 2013Pion et al , 2014Oulame et al 2015;Barbara et al 2015;Nguyen et al 2015;Maiorana et al 2016;Reano et al 2016), copolymer with methacrylic acid (Iemma et al 2010), and liquid-crystalline forms (Wang et al 2012). Ferulic acid has many physiological functions including antimicrobial, anti-oxidant, anti-thrombotic, and carcinostatic activities; it has been studied for its applications in the food, cosmetic, and pharmaceutical fields (Ou and Kwok 2004;Pei et al 2015;Takahashi et al 2015).…”

Section: Introductionmentioning

confidence: 99%

Bio-based Polymer from Ferulic Acid by Electropolymerization

et al. 2016

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Electropolymerization was carried out in order to obtain a bio-based polymer by a simple procedure. Ferulic acid, a component of gramineous plants, was selected for this purpose. A thin polymer film was produced in an organic solvent medium (i.e., CH2Cl2/methanol (4:1 v/v) in the presence of 0.2 M LiClO4), whereas it was not obtained in a totally aqueous medium (0.2 M NaOH). Scanning electron microscopic analysis showed that the polymer film had a porous lamellar structure of ~10 μm thickness. Most of the carboxyl groups remained, and IR spectroscopy and time-of-flight secondary ion mass spectrometry (TOF-SIMS) analyses revealed that oquinones existed in the polymer film. After electropolymerization, caffeic acid, sinapic acid, 3,6-bis(4-hydroxy-3-methoxyphenyl)tetrahydrofuro [3,4-c]furan-1,4-dione (1), and 4,4'-dihydroxy-3,3'-dimethoxy-β,β'-bicinnamic acid (2) were detected in the organic reaction medium; this suggested that demethylation, methoxyl group addition, and radical coupling reactions occurred at the electrode surface.

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Section: Introductionmentioning

confidence: 99%

Bio-based Polymer from Ferulic Acid by Electropolymerization

et al. 2016

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“…116 Analogues of PET have recently been reported using lignin-based monomers and acetic acid. 117 After removal of acetic acid in Figure 13, the resulting polyesters had similar thermal properties as PET.…”

Section: Part 5: Condensation-type Monomersmentioning

confidence: 98%

How well can renewable resources mimic commodity monomers and polymers?

Mathers

2011

J. Polym. Sci. A Polym. Chem.

223

100

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This highlight discusses the recent progress aimed at maximizing the potential of biomass for commodity monomers and polymers. These efforts are no longer solely academic issues. In recent years, a variety of alkene, diene, aromatic, and condensation type monomers have utilized renewable resources, such as cellulose, lignin, plant oils, starches, and monoterpenes in commercial polymers. Generally, these multifaceted efforts involve pretreatment of biomass with thermal, chemical, or physical methods followed by a catalyst sequence that entails a combination of acid-catalysis, bio-catalysis, or metal-based catalysis. In this regard, synthesis strategies for ethylene, propylene, a-olefins, methylmethacrylate, 1,3-butadiene, 1,3-cyclohexadiene, isoprene, 1,3-propanediol, 1,4-butanediol, and terephthalic acid are discussed as well as opportunities for other renewable-based monomers. V C 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 50: [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15] 2012

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“…In 2010, the synthesis of bio-renewable PET mimics, synthesized from lignin and acetic acid was reported [321]. In particular, vanillin and acetic anhydride were employed and through the production of acetyldihydroferulic acid a homo-polymerization was conducted.…”

Section: Valorization Of Ferulic Acid (Fa) and Aromatic Compounds Asmentioning

confidence: 99%

Processing, Valorization and Application of Bio-Waste Derived Compounds from Potato, Tomato, Olive and Cereals: A Review

Fritsch

Stäbler

Happel³

et al. 2017

Sustainability

157

102

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Abstract:The vast and ever-growing amount of agricultural and food wastes has become a major concern throughout the whole world. Therefore, strategies for their processing and value-added reuse are needed to enable a sustainable utilization of feedstocks and reduce the environmental burden. By-products of potato, tomato, cereals and olive arise in significant amounts in European countries and are consequently of high relevance. Due to their composition with various beneficial ingredients, the waste products can be valorized by different techniques leading to economic and environmental advantages. This paper focuses on the waste generation during industrial processing of potato, tomato, cereals and olives within the European Union and reviews state-of-the-art technologies for their valorization. Furthermore, current applications, future perspectives and challenges are discussed.

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Biorenewable polyethylene terephthalate mimics derived from lignin and acetic acid

Cited by 205 publications

References 14 publications

Bio-based Polymer from Ferulic Acid by Electropolymerization

Bio-based Polymer from Ferulic Acid by Electropolymerization

How well can renewable resources mimic commodity monomers and polymers?

Processing, Valorization and Application of Bio-Waste Derived Compounds from Potato, Tomato, Olive and Cereals: A Review

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