1982
DOI: 10.1002/anie.198208340
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Bis(pentafluor-?6-sulfanyl)amine

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Cited by 4 publications
(3 citation statements)
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“…The most striking feature of the SF 5 NO 2 structure is an extremely long S−N bond of 1.903(7) Å. This bond is more than 0.2 Å longer than those in pentafluorosulfenylamines, such as SF 5 NF 2 (1.691(5) Å), (SF 5 ) 2 NF (1.685(5)Å), , and in the radical (SF 5 ) 2 N• (1.692(4) Å) . It is even longer than the S−N bond in the highly strained tris(pentafluorosulfenyl)amine, (SF 5 ) 3 N (1.829(6) Å) .…”
Section: Resultsmentioning
confidence: 95%
“…The most striking feature of the SF 5 NO 2 structure is an extremely long S−N bond of 1.903(7) Å. This bond is more than 0.2 Å longer than those in pentafluorosulfenylamines, such as SF 5 NF 2 (1.691(5) Å), (SF 5 ) 2 NF (1.685(5)Å), , and in the radical (SF 5 ) 2 N• (1.692(4) Å) . It is even longer than the S−N bond in the highly strained tris(pentafluorosulfenyl)amine, (SF 5 ) 3 N (1.829(6) Å) .…”
Section: Resultsmentioning
confidence: 95%
“…Synthesis of 37a was accomplished by fluorination of NSF 3 with F 2 to form 36 , followed by further reaction with HF . The haloamines 37b and 37c were formed by reaction of 38 with ClF or F 2 , respectively. , …”
Section: Synthesis Of Aliphatic R–sf4–r′ and R–sf5 Compounds By Fluor...mentioning
confidence: 99%
“…20a Higher yields of 25 were obtained when 23 reacted with F 2 in the presence of CsF at −15 °C. The increased yield has been attributed to the stability of the intermediate salt that is formed (26), which is more stable than 24, allowing for further conversion to 25. 20b Larger perfluoroalkyl-SF 5 compounds were synthesized from the corresponding thiol or sulfide and F 2 (Scheme 7).…”
Section: Initial Access To Aliphatic R−sf 5 Compoundsmentioning
confidence: 99%