Bis(μ-4,6-dimethylpyrimidine-2-thiolato)-κ³N,S:S;κ³S:N,S-bis[(triphenylphosphane-κP)silver(I)]

Abstract

Key indicators: single-crystal X-ray study; T = 293 K; mean (C-C) = 0.004 Å; R factor = 0.032; wR factor = 0.088; data-to-parameter ratio = 20.9.The dinuclear title complex, [Ag 2 (C 6 H 7 N 2 S) 2 (C 18 H 15 P) 2 ], comprises two inversion-related [Ag(C 6 H 7 N 2 S)(C 18 H 15 P)] units. The pyrimidinethiolate anion acts both as a bridging and a chelating ligand. The Ag I ions are linked via two 2 -S donor atoms, which generate a strictly planar Ag 2 S 2 core with an AgÁ Á ÁAg separation of 2.9569 (4) Å . The Ag I ion presents a distorted tetrahedral coordination geometry. In the crystal, weak C-HÁ Á ÁN and C-HÁ Á ÁS hydrogen bonds link the complex molecules into a two-dimensional network parallel to (010). Related literature

A two-dimensional silver(I) coordination polymer constructed from 4-aminophenylarsonate and triphenylphosphane: poly[[(μ3-4-aminophenylarsonato-κ3N:O:O)(triphenylphosphane-κP)silver(I)] monohydrate]

“…1 (Yang et al, 2004;. The Ag-P bond length is similar to those observed in other Ag-PPh 3 compounds (Ceamanos et al, 2012;Wattanakanjana et al, 2012). The Ag-N bond length is somewhat longer than values reported previously for Aganiline compounds (Schreuer, 1999;Johnson et al, 2002).…”

“…1, the Ag I centre is four-coordinated by one PPh 3 P atom and by one amine N atom and two arsonate O atoms from three Hapa À ligands, displaying a severely distorted [AgNPO 2 ] tetrahedral arrangement; the Ag-O/N/P distances are in the range 2.346 (2)-2.506 (2) Å and the O/N/P-Ag-O/N/P angles (Yang et al, 2004;. The Ag-P bond length is similar to those observed in other Ag-PPh 3 compounds (Ceamanos et al, 2012;Wattanakanjana et al, 2012). The Ag-N bond length is somewhat longer than values reported previously for Aganiline compounds (Schreuer, 1999;Johnson et al, 2002).…”

Crystal structure of chlorido[1-(4-nitrophenyl)thiourea-κS]bis(triphenylphosphane-κP)silver(I)

“…1). The Ag-S bond length of 2.6316 (5) is similar to that of 2.603 (4) Å found in [Ag 2 Cl 2 (CH 5 N 3 S) 2 (C 18 H 15 P) 2 ], (Wattanakanjana et al, 2012). An intramolecular N2-H2BÁ Á ÁCl1 hydrogen bond with graph-set motif S(6) is observed (Table 1).…”

Di-μ-thiosemicarbazide-κ4S:S-bis[chloridobis(triphenylphosphane-κP)silver(I)]

“…The molecular structure of the title dinuclear compound is shown in Fig. 1 4Å is slightly longer than that found in for example [Ag 2 (C 6 H 7 N 2 S) 2 (C 18 H 15 P) 2 ], which is 2.4088 (6) Å (Wattanakanjana et al, 2012). The bridging Ag-S bond length (Ag1-S1 = 2.5202 (4) Å) is shorter than those observed in related silver(I) complexes containing S-bridged donor ligand, due to 2.5832 8 (Fig.…”

“…For potential applications of thiosemicarbazide derivatives and their metal complexes, see: Pandeya et al (1999); Wujec et al (2009); Mohareb & Mohamed (2012); He et al (2012). For examples of related discrete complexes, see: Wattanakanjana et al (2012); Lobana et al (2008).…”