Polymer monoliths are promising materials for sample preparation due to their high porosity, pH stability, and simple preparation. The use of melamine formaldehyde foams has been reported as an effective support to prepare highly robust silica and polymer monoliths. Herein, divinylbenzene monoliths based on a 50:50 (%, w/w) crosslinker/porogen ratio have been nested within a melamineâformaldehyde sponge, resulting in monoliths with a surface area higher than 400 m2/g. The extraction performance of these monoliths was evaluated for the extraction of endocrineâdisrupting bisphenols from aqueous solutions. We evaluated for the first time the versatility of spongeânested polymer monoliths by comparing three different extraction modes (vortex mixing, magnetic stirring, and orbital shaking). Vortex mixing showed a comparable recovery of bisphenols (39%â81%) in a shorter extraction time (30Â min, instead of 2Â h). In addition, the robustness of the spongeânested polymer monoliths was demonstrated for the first time by reshaping a larger monolithic cube (0.125 cm3) into four smaller pieces (4Â ĂÂ 0.03125 cm3) leading to a 16%â21% increase in extraction efficiency. This effect was attributed to an increase in the effective contact area with the sample, obtaining a higher analyte extraction capacity.