Block copolymers for waterborne coatings—A novel eco-friendly approach for improved coating adhesion to untreated polypropylene based plastics

Schellekens, Mike A. J.; Twene, Derrick; Waals, Adri van der

doi:10.1016/j.porgcoat.2011.03.007

Cited by 23 publications

(11 citation statements)

References 13 publications

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“…A* (CMS) [336] (AA) [499] BA [500,501] NIPAm [499] TMAPAm [499] (DMAm) [494] VAc [494,502,503] VBz [503] VPv [503] NES [290] BES [290] VF2 [504] NVC [290] NVCL [505] NVP [506,507] VPA [506,508] (DADMAC) [113,506] (AA/iBoA) [509] (AA-b-iBoA) [509] VF2/PMVE [504] DMAm-b-VAc [494] (PDMAm-b-VF2) [504] VAc-b-VBz [503] (VAc-b-VPv) [503] VBz-bVAc [503] VBz-b-VPv [503] VPv-b-VAc [503] (VPv-bVBz) [503] NVC-b-NES [290] AA-b-VPA [508] (Am-b-DADMAC) [113] (AA-b-DADMAC) [506] 228…”

Section: O S S Cnmentioning

confidence: 99%

Living Radical Polymerization by the RAFT Process – A Third Update

2012

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This paper provides a third update to the review of reversible deactivation radical polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC(¼S)SR) by a mechanism of reversible addition-fragmentation chain transfer ( Chem. 2009Chem. , 62, 1402. This review cites over 700 publications that appeared during the period mid 2009 to early 2012 covering various aspects of RAFT polymerization which include reagent synthesis and properties, kinetics and mechanism of polymerization, novel polymer syntheses, and a diverse range of applications. This period has witnessed further significant developments, particularly in the areas of novel RAFT agents, techniques for end-group transformation, the production of micro/nanoparticles and modified surfaces, and biopolymer conjugates both for therapeutic and diagnostic applications.

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Section: O S S Cnmentioning

confidence: 99%

Living Radical Polymerization by the RAFT Process – A Third Update

2012

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“…Mengatasi permasalahan kompatibilitas antara resiprene-35 dan PP dapat dilakukan dengan teknik grafting, beberapa jenis adhesion promoter diperoleh melalui teknik blok kopolimer dan grafting. Umumnya adhesion promoter yang dikembangkan menggunakan turunan akrilat, seperti isobornil akrilat dengan asam akrilat, butil metakrilat, dan butil akrilat [4,5]. Pada penelitian ini akan dilakukan modifikasi resiprene-35 dengan asam metakrilat melalui teknik grafting dengan kehadiran DVB menggunakan sistem pelarut.…”

Section: Pendahuluanunclassified

Modifikasi Resiprene-35 Dengan Asam Metakrilat Melalui Teknik Pencangkokan Dalam Sistem Pelarut

Mahendra

Wijosentono

Tamrin

et al. 2019

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Modifikasi R-35 dilakukan dengan menggunakan monomer olefin turunan akrilat, yakni asam metakrilat. Tujuan modifikasi R-35 menggunakan asam metakrilat adalah untuk memperoleh material adhesion promoter yang sesuai untuk karet alam siklis yang kedepannya diharapkan dapat dimanfaatkan sebagai bahan cat untuk permukaan poliolefin. Proses modifikasi R-35 dengan monomer asam metakrilat dilakukan dalam sistem pelarut pada temperatur 110-140 °C dan desain eksperimental dirancang dengan menggunakan software Qualitek V.4.0. Analisis material R-35 termodifikasi dilakukan dengan menggunakan FTIR dan 1 H-NMR. Analisis FTIR menunjukkan puncak khas daripada ikatan O-H, C-C, C=O, C=C, dan C-O yang mewakili keberadaan daripada R- 35, asam metakrilat dan divinilbenzena. Analisis lebih lanjut %G dengan software Qualitek V.4.0. menunjukkan bahwa %G tertinggi dapat dicapai dengan mengkondisikan reaksi pada T = 140 °C, %MAA = 20%, %DVB = 20, dan t = 180 menit, dengan estimasi %G yang diperoleh adalah 26.08%. Modification of Resiprene-35 (R-35) was carried out using the monomer of olefin acrylic derivative, namely methacrylic acid. The purpose of the modification of the R-35 using methacrylic acid was to obtain an adhesion promoter material suitable for cyclic natural rubber which in the future is expected to be used as a paint material for polyolefin surfaces. The modification process of R-35 with methacrylic acid monomer was carried out in a solvent system at a temperature of 110-140 °C and the experimental design was designed using Qualitek V.4.0 software. The analysis of modified R-35 material was carried out using FTIR and 1 H-NMR. FTIR analysis showed typical peaks rather than O-H, C-C, C = O, C = C, and C-O bonds which represented the presence of R-35, methacrylic acid, and divinylbenzene. Further analysis %G with Qualitek V.4.0 software showed that the highest %G could be achieved by conditioning the reaction at T = 140 °C % MAA = 20%, % DVB = 20%, and t = 180 minutes, with an estimated %G obtained, was 26.08%.

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“…In the experiment, butyl acrylate (BA) is selected as the soft monomer to endow the stickiness and movement ability to the adhesive, while isobornyl acrylate (IBOA) is selected as the hard monomer to provide rigidity to the adhesive. In addition, because of its large side groups, IBOA can improve the flowability of adhesive and IBOA has a good compatibility with PP . Moreover, hydroxypropyl methacrylate is chosen as a functional monomer.…”

Section: Introductionmentioning

confidence: 99%

Reversible adhesives based on acrylate copolymer modified by caffeic acid containing boroxin

Zhang

Bai

Liu

2019

J of Applied Polymer Sci

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4‐formyl‐phenylboronic acid (FBA) and caffeic acid (CA) can combine to obtain a novel vinyl monomer containing boroxin, which was named as FBCA. Having been reduced the inhibition of phenolic hydroxyl groups, FBCA could directly copolymerize with acrylate (for instance, isobornyl acrylate (IBOA), butyl acrylate (BA), and hydroxypropyl methacrylate (HPMA)) by free‐radical polymerization to produce modified acrylate copolymer adhesive (FBCA‐IBH). Compared with sole acrylate copolymer adhesive (IBH), the FBCA‐IBH adhesive presents a higher thermal stability, cohesive strength, creep resistance, strain recovery, and adhesion strength to different substrate (such as carbon steel, polypropylene (PP), and polytetrafluoroethylene (PTFE)). According to the results of TGA, the initial degradation temperature of FBCA‐IBH is increased by 50 °C. The creep resistance of FBCA‐IBH is improved and its holding power to carbon steel is increased from 19 min to 3 h. It is eye catching that the shear strength to carbon steel could reach 9.37 MPa. Besides, this shear strength can be maintained even if after 18 cycle times, even the maximum value can achieve 14.36 MPa. The adhesion of thermoplastic adhesives to carbon steel exhibits adhesion strength comparable to that of thermoset adhesives. The reversible adhesive presents bonding strength in macro‐field, not just limited in micro‐field. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 137, 48703.

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Block copolymers for waterborne coatings—A novel eco-friendly approach for improved coating adhesion to untreated polypropylene based plastics

Cited by 23 publications

References 13 publications

Living Radical Polymerization by the RAFT Process – A Third Update

Living Radical Polymerization by the RAFT Process – A Third Update

Modifikasi Resiprene-35 Dengan Asam Metakrilat Melalui Teknik Pencangkokan Dalam Sistem Pelarut

Reversible adhesives based on acrylate copolymer modified by caffeic acid containing boroxin

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