Bonding in titanocenyl complexes containing O,O′‐cyclic ligands

A (t Bu-DAC)Ir(COD)Cl complex (t Bu-DAC = 1,3-bis(N-tert-butyl)diamidocarbene, COD = 1,5-cyclooctadiene) reacts with titanocene(II) and zirconocene(II) sources to form heterobimetallic complexes by metallocene coordination at the remote oxalamide binding site. Structural and spectroscopic data reveal the formation of a doubly-reduced [ t Bu-DAC] 2ligand upon metallocene complexation. The metallocene-substituted complexes catalyze benzaldehyde hydrosilation at rates over an order of magnitude faster than those observed with the parent iridium complex.

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Bonding in titanocenyl complexes containing O,O′‐cyclic ligands

Cited by 4 publications

References 12 publications

Electrochemical and density functional theory study of bis(cyclopentadienyl) mono(β-diketonato) titanium(IV) cationic complexes

Electrochemical and density functional theory study of bis(cyclopentadienyl) mono(β-diketonato) titanium(IV) cationic complexes

Characterization of [Rh(PhCOCHCOCH2CH2CH3)(CO)2] by X-ray crystallography, a computational and a statistical study

Functionalization of an iridium–diamidocarbene complex by ligand-based reactions with titanocene and zirconocene sources

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