2023
DOI: 10.1002/chem.202302060
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Boron Polycation Supported by Cyclic Bis(carbodiphosphorane)

Abstract: A novel cyclic bis(carbodiphosphorane) ligand was prepared and investigated in coordination with group 13 elements, B, Al and Ga. Al and Ga afforded dinuclear adduct where two metal centers were bridged by the bis(carbodiphosphorane) ligand. In contrast, the reaction with boron trichloride afforded a monomeric dicationic three‐coordinate boron species composed of one boron moieties and one ligand. The structures of these products were determined by X‐ray crystallography. In the dicationic boron compound, the s… Show more

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