Bridged Macrocyclic Transition Metal Complexes as Semiconducting Materials

Photoredox pathways to spatially restricted metallopolymeric films

“…Each diphosphine occupies an equatorial and an axial site. The Rh-P distances range from 2.195 (2) to 2.367 (2) A, with the longest Rh-P trans to the Rh-Rh bond, and are comparable with the values found in other dirhodium(II,II) derivatives.1 The values of 163.06 (6) and 157.2 (2)°f or the Rh(2)-Rh-…”

“…Ruin(bpy-pyr)2(bpy--pyr)2+* (5) Rum(bpy-pyr)2(bpy'"-pyr)2+* + MV2+ -* Run,(bpy-pyr)33+ + MV+ (6) Ruin(bpy-pyr)33+ -* Run(bpy-pyr)2(bpy-pyr+)3+ (7) «Run(bpy-pyr)2(bpy-pyr+)3+poly-Run(bpy-pyr)3m+ + nli+ (8) Rum(bpy-pyr)33+ + MV+ -* Run(bpy-pyr)32+ + MV2+ (9a)…”