C–H and C–C bonds activation by iridium clusters: Synthesis and solid state structure of [Ir6(CO)14(μ3-η1:η2:η1-C7H8)]

The reaction of the heteronuclear cluster RuOs3(μ‐H)2(CO)13 with saturated and unsaturated C5 rings led to the aromatization of the rings to afford the clusters RuOs3(μ‐H)(CO)9(μ‐CO)2(η5‐C5R4R′). However, the reaction with cyclopentene gave the cluster RuOs3(μ‐H)3(CO)11(μ,η1:η2‐C5H7) via C–H activation of an sp2 carbon instead. Thermolysis of two of the products, RuOs3(μ‐H)(CO)9(μ‐CO)2(η5‐Cp′) and RuOs3(μ‐H)(CO)9(μ‐CO)2(η5‐C5H4SiMe3), led to their isomerization to butterfly clusters.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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The Aromatization of C₅ Rings on a Heteronuclear Cluster

Tan

Leong

2007

Eur J Inorg Chem

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Advances in the chemistry of alkyne-substituted homo- and heterometallic carbonyl clusters of the iron, cobalt and nickel triads. An update

Gervasio

Sappa

Secco

2014

Journal of Organometallic Chemistry

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[(η³-Bi₃)₂(IrCO)₆(μ₄-Bi)₃]³⁻: a new archetype of a 15-vertex deltahedral hybrid from Bi_x^x−-coordination aggregation of cationic [IrCO]⁺ units

Liu

et al. 2019

Dalton Trans.

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C–H and C–C bonds activation by iridium clusters: Synthesis and solid state structure of [Ir6(CO)14(μ3-η1:η2:η1-C7H8)]

Cited by 3 publications

References 36 publications

The Aromatization of C₅ Rings on a Heteronuclear Cluster

The Aromatization of C₅ Rings on a Heteronuclear Cluster

Advances in the chemistry of alkyne-substituted homo- and heterometallic carbonyl clusters of the iron, cobalt and nickel triads. An update

[(η³-Bi₃)₂(IrCO)₆(μ₄-Bi)₃]³⁻: a new archetype of a 15-vertex deltahedral hybrid from Bi_x^x−-coordination aggregation of cationic [IrCO]⁺ units

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C–H and C–C bonds activation by iridium clusters: Synthesis and solid state structure of [Ir6(CO)14(μ3-η1:η2:η1-C7H8)]

Cited by 3 publications

References 36 publications

The Aromatization of C5 Rings on a Heteronuclear Cluster

The Aromatization of C5 Rings on a Heteronuclear Cluster

Advances in the chemistry of alkyne-substituted homo- and heterometallic carbonyl clusters of the iron, cobalt and nickel triads. An update

[(η3-Bi3)2(IrCO)6(μ4-Bi)3]3−: a new archetype of a 15-vertex deltahedral hybrid from Bixx−-coordination aggregation of cationic [IrCO]+ units

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The Aromatization of C₅ Rings on a Heteronuclear Cluster

The Aromatization of C₅ Rings on a Heteronuclear Cluster

[(η³-Bi₃)₂(IrCO)₆(μ₄-Bi)₃]³⁻: a new archetype of a 15-vertex deltahedral hybrid from Bi_x^x−-coordination aggregation of cationic [IrCO]⁺ units