2020
DOI: 10.1039/d0dt00587h
|View full text |Cite
|
Sign up to set email alerts
|

Cage-like silsesquioxanes-based hybrid materials

Abstract: This Perspective reviews recent advances in cage-like silsesquioxanes-based hybrid materials, ranging from monomer functionalization and materials preparation to application.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
4

Citation Types

0
113
0

Year Published

2020
2020
2023
2023

Publication Types

Select...
9

Relationship

0
9

Authors

Journals

citations
Cited by 178 publications
(113 citation statements)
references
References 129 publications
0
113
0
Order By: Relevance
“…To improve either processing or service properties of PE or composites thereof, additives such as lubricants, compatibilisers, plasticizers, or antioxidants/stabilizers have been extensively used [ 10 ]. As a novel type of either processing/functional additives or nanoreinforcing agents for polymer (nano)composites or blends, polyhedral oligomeric silsesquioxanes (SSQ) have been reported several times over the last twenty years, and discussed in detail in reviews by Kausar [ 11 ], Du [ 12 ], Kuo [ 13 ], Ayandele [ 14 ], Zhou [ 15 ], Shi [ 16 ], and Li [ 17 ]. Polyhedral oligomeric silsesquioxanes are known for their well-defined, molecular structure, controllable physicochemical properties on the basis of the introduced organic substituents, good solubility and dispersion properties, or simple, reproducible synthetic protocols [ 18 , 19 ].…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…To improve either processing or service properties of PE or composites thereof, additives such as lubricants, compatibilisers, plasticizers, or antioxidants/stabilizers have been extensively used [ 10 ]. As a novel type of either processing/functional additives or nanoreinforcing agents for polymer (nano)composites or blends, polyhedral oligomeric silsesquioxanes (SSQ) have been reported several times over the last twenty years, and discussed in detail in reviews by Kausar [ 11 ], Du [ 12 ], Kuo [ 13 ], Ayandele [ 14 ], Zhou [ 15 ], Shi [ 16 ], and Li [ 17 ]. Polyhedral oligomeric silsesquioxanes are known for their well-defined, molecular structure, controllable physicochemical properties on the basis of the introduced organic substituents, good solubility and dispersion properties, or simple, reproducible synthetic protocols [ 18 , 19 ].…”
Section: Introductionmentioning
confidence: 99%
“…Among other methods, ball milling [ 30 , 31 , 33 , 37 ], solution blending [ 34 , 35 ], or reactive melt blending [ 51 , 52 ] have been reported with moderate to good results. The dispersion level plays a huge factor on the properties of the obtained materials, and effective dispersing of the organosilicon additive is crucial to observe effects such as (nano)reinforcing action or thermal stabilization of the composition [ 11 , 12 , 13 , 14 , 15 ]. In the previous work, we showed how a proper choice of organic substituents for spherosilicate compounds, as well as a processing method applied, allowed for effective obtaining of micro-and nanodispersion of the compounds in PE together with limited agglomeration [ 54 ].…”
Section: Introductionmentioning
confidence: 99%
“…In this regard, polyhedralo ligomeric silsesquioxanes (POSS) have emergeda savaluableg roup of 3D nano-building-blocks for the fabrication of av ariety of hybrid functional materials. [15][16][17][18][19] Several prime qualifications make POSS the appropriate choice for its use as principal core:( i) it exhibits high stability and excellent biocompatibility in ab iological environment, [20] (ii)the inorganic cage providesn ot only protection to the covalently attached dye from stabilityb ut also ac onvenient framework for 3D multivalent display of pendant epitopes, [21] (iii)facile functionalization. [22] The highly symmetrical and topologically ideal cubic-octameric framework (T8), with general formula (RSiO1.5) 8 and ac age size of approximately 0.5-0.7 nm has been reported as suitable precursor.…”
mentioning
confidence: 99%
“…Over the last 30 years, the chemistry of these compounds has been explored to some extent . Silsesquioxane‐based hybrid materials have been a subject of detailed reviews . Silsesquioxanes in which one or more silicon atoms in the core are replaced with boron atoms are called borasilsesquioxanes.…”
Section: Introductionmentioning
confidence: 99%