Capillary GC/helium microwave emission detector characterization of fluorine containing metabolites in blood plasma

Hagen, D.F.; Belisle, Jon; Marhevka, John S.

doi:10.1016/0584-8547(83)80136-0

Cited by 28 publications

(2 citation statements)

References 11 publications

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“…(b) Elevated Background Excitation and Emission. It is possible that complete molecular fragmentation also occurs at the lower power levels (10,14,15). If this is the case, then the higher power available from the moderate power discharge may be further exciting the molecular background of the sample and thereby degrading the S/N (resulting in higher detection limits), (c) Optical Coupling.…”

Section: Resultsmentioning

confidence: 99%

Moderate-power helium plasma as an element-selective detector for gas chromatography of dioxins and other halogenated compounds

Haas¹,

Caruso²

1985

Anal. Chem.

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Section: Resultsmentioning

confidence: 99%

Moderate-power helium plasma as an element-selective detector for gas chromatography of dioxins and other halogenated compounds

Haas¹,

Caruso²

1985

Anal. Chem.

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“…The following analysis of the fluorine content as fluoride was performed utilizing LC-ICP-MS. Fluorine content was determined in leaves, milk powder, and marine tissue. Detection limits obtained for fluorine were A different application for fluorine speciation was reported by Hagen and colleagues [93]. In this case, GC-MIP-OES was applied for the separation and determination of fluorine-containing metabolites in rat blood plasma samples.…”

Section: Determination Of Fluorine-containing Speciesmentioning

confidence: 96%

Speciation Analysis of Non-Metallic Elements Using Plasma-Based Atomic Spectrometry for Detection

Wuilloud¹,

Altamirano

2006

CAC

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In this review, a full discussion and update of the state-of-the-art of separation techniques interfaced to plasma spectrometers for speciation analysis of non-metallic elements, such as iodine, chlorine, bromine and fluorine as well as phosphorus and sulfur is presented. The plasma-based techniques covered include inductively coupled plasma mass spectrometry (ICP-MS) microwave-induced plasma optical emission spectrometry (MIP-OES), and inductively coupled plasma optical emission spectrometry (ICP-OES). Also, different variants of plasma sources, such as low power plasmas and glow discharge (GD) sources are described and compared with respect to their capabilities in elemental speciation. Recent advances and alternative mass analyzers (collision/reaction cell; time-of-flight; double-focusing sector field) are also included. The discussion is centralized on the application of the hyphenated methodologies involving several types of separations such as liquid chromatography, gas chromatography and electrophoresis coupled to plasma-based detectors for speciation analysis of non-metals. This is presented in different sections considering the analysis of several matrices including environmental, biological and food samples, as well as a last section related to the use of halogenated compounds for plasma studies.

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Enhanced sensitivity and selectivity of a gas chromatography-microwave-induced plasma atomic emission system (GC-MIP) at the 685.6-nm fluorine emission line

Augusto

Valente

1999

J. Micro. Sep.

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Capillary GC/helium microwave emission detector characterization of fluorine containing metabolites in blood plasma

Cited by 28 publications

References 11 publications

Moderate-power helium plasma as an element-selective detector for gas chromatography of dioxins and other halogenated compounds

Moderate-power helium plasma as an element-selective detector for gas chromatography of dioxins and other halogenated compounds

Speciation Analysis of Non-Metallic Elements Using Plasma-Based Atomic Spectrometry for Detection

Enhanced sensitivity and selectivity of a gas chromatography-microwave-induced plasma atomic emission system (GC-MIP) at the 685.6-nm fluorine emission line

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