2024
DOI: 10.1021/acs.jpca.3c07961
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Carbon-Atom Exchange between [MC2]+ (M = Os and Ir) and Methane: on the Thermodynamic and Dynamic Aspects

Shihan Li,
Chao Qian,
Xiao-Nan Wu
et al.

Abstract: Gas-phase reactions of [OsC 2 ] + and [IrC 2 ] + with methane at ambient temperature have been studied using quadrupole-ion trap mass spectrometry combined with quantum chemical calculations. Both [OsC 2 ] + and [IrC 2 ] + undergo carbon-atom exchange reactions with methane. The associated mechanisms for the two systems are found to be similar. The differences in the rates of carbon isotope exchange reactions of methane with [MC 2 ] + (M = Os and Ir) are explained by several factors like the energy barrier for… Show more

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