Carbon-chain polymers and copolymers Communication 5. Synthesis and properties of copolymers of acrylonitrile with methyl methacrylate

Kolesnikov, G. S.; Fedorova, L. S.; Tsetlin, B.L.; Klimentova, N. V.

doi:10.1007/bf01150811

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1960

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“…Kolesnikov et aZ. 20 have recently examined the thermomechanical properties of random copolymers of methyl methacrylate and acrylonitrile. We have derived values for the glass temperature from their data by extrapolating the linear part of the deformation-temperature curve to zero deformation.…”

Section: Discussionmentioning

confidence: 99%

Physical properties of vinyl polymers. Part 2.—The glass-transition temperature of block and random acrylonitrile + methyl methacrylate copolymers

Beevers¹,

White²

1960

Trans. Faraday Soc.

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The glass-transition temperature of methyl methacrylate and acrylonitrile block and random copolymers is shown to be sensitive to the structural arrangement in the copolymer. Block copolymers have glass temperatures which are intermediate between those of polyacrylonitrile and polymethylmethacrylate whereas the random copolymers have glass temperatures which fall below that of either homopolymer. Results show that the acrylonitrile block, to a large extent, governs the properties of the block copolymer.

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Section: Discussionmentioning

confidence: 99%