In recent years, the No. 1 document of the Chinese Party Central Committee has repeatedly mentioned the need to strengthen the agricultural logistics industry and the rapid and healthy development of the cold chain logistics industry, and it is urgent to establish and cultivate some agricultural cold chain logistics enterprises with market competitiveness. In this paper, by considering the green development of enterprises and combining the connotation characteristics of agricultural cold chain logistics, the efficiency of Chinese agricultural cold chain logistics enterprises is evaluated by using a combination of intuitionistic fuzzy and DEMATEL methods, starting from five secondary indicators (financial, customer, green, cold chain operation and technological development) with 15 specific influencing factors, based on the research results showing: cold storage utilization rate, reefer truck utilization rate and total asset turnover rate are the three key factors affecting their development. Based on this, W listed enterprises are used as the example to propose corresponding countermeasures in terms of improving the efficiency of cold chain operations, strengthening green capabilities and attaching importance to the construction of intelligent logistics, to promote the sustainable development of China's agricultural cold chain logistics enterprises.