Catalytic Carbonylations in Ionic Liquids

Consorti, Crestina S.; Dupont, Jaı̈rton

doi:10.1002/9783527621545.ch6

Cited by 4 publications

(1 citation statement)

References 103 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Although hydroformylation was the most thoroughly explored transition metalcatalysed carbonylation reaction in ILs, other carbonylations -especially those based on palladium catalyst precursors -such as alkoxy-and aminocarbonylation of alkenes and aryl halides have also been investigated [5,6]. This chapter is intended to review briefly the progress of research since the first report on alkoxycarbonylation carried out in ILs by Dupont in 1998 [7].…”

Section: Introductionmentioning

confidence: 98%

ILs in Transition Metal-Catalysed Alkoxy- and Aminocarbonylation

Skoda‐Földes

2013

Ionic Liquids (ILs) in Organometallic Catalysis

View full text Add to dashboard Cite

The use of carbon monoxide as a carbonyl source for the preparation of aldehydes, ketones and carboxylic acid derivatives in homogeneous catalytic reactions is a valuable tool in the synthesis of fine chemicals. Amongst immobilising agents for carbonylation catalysts, the application of ILs drew particular attention. Besides enabling catalyst reuse, the ionic liquid may influence the structure of catalysts or catalyst precursors, may affect the chemoselectivity of the reaction or may be capable of solubilising special substrates. The present chapter is intended to summarise the research carried out in the past 15 years involving carbonylation reactions of alkenes/alkynes and aryl/alkenyl halides in the presence of various nucleophiles, such as alcohols, water, amines and thiols.

show abstract

Section: Introductionmentioning

confidence: 98%