2022
DOI: 10.26434/chemrxiv-2022-7cztk
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Cationic Tetrylene-Iron(0) Complexes: Access Points for Cooperative, Reversible Dihydrogen Activation and Open-Shell Iron(-I) Ferrato-Tetrylenes

Abstract: The oxidative addition of catalytically relevant small molecules in molecular iron complexes poses a considerable challenge in achieving ‘precious metal catalysis’ utilizing this Earth abundant metal. Here, we show that non-innocent ligands based upon cationic heavier tetrylenes, EII (E = Ge, Sn), can work in synergy with a reactive iron center for the oxidative cleavage of inert bonds. Specifically, the open-shell cationic stannylene-iron(0) complex 4 (4 = [PhiPDippSn·Fe·IPr]+; PhiPDipp = {[Ph2PCH2Si(iPr)2](D… Show more

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