1998
DOI: 10.1295/koron.55.519
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Chain-Folding Conformations in Isotactic Polypropylene.

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“…If o ne considers the crys tallog raphy of T -polypropylene, there is a st rict o rder of packing o f helices [17 ~ 19] , and in additio n chain folding of PP and the packing of righ t-and left-handed helices in the crys tal are v ery clo sely related [ 20] . The com m onest tacticity def ects appear as a pai r of syndiotactic diads w hich preserve the directionality of the iso tactic chain [ 17] , and even if not included in the crystal w ould allow the same adjacent reent ry but w ith a loop ins tead o f a tight fold.…”
Section: Resultsmentioning
confidence: 99%
“…If o ne considers the crys tallog raphy of T -polypropylene, there is a st rict o rder of packing o f helices [17 ~ 19] , and in additio n chain folding of PP and the packing of righ t-and left-handed helices in the crys tal are v ery clo sely related [ 20] . The com m onest tacticity def ects appear as a pai r of syndiotactic diads w hich preserve the directionality of the iso tactic chain [ 17] , and even if not included in the crystal w ould allow the same adjacent reent ry but w ith a loop ins tead o f a tight fold.…”
Section: Resultsmentioning
confidence: 99%