Reaction of Ta(NMe2)5 with 5 equivalents of pyrazole (Hpz) in toluene unexpectedly resulted in metal reduction from Ta(V) to Ta(IV) and formation of homoleptic binuclear pyrazolate [Ta2(pz)8] (1). Despite elongated...
Reaction of Ta(NMe2)5 with 5 equivalents of pyrazole (Hpz) in toluene unexpectedly resulted in metal reduction from Ta(V) to Ta(IV) and formation of homoleptic binuclear pyrazolate [Ta2(pz)8] (1). Despite elongated...
O-centered tetranuclear vanadium selenoiodide [V4OSe8I5]∞ (1) was synthesized by an ampoule method from the elements with addition of water. Its X-ray crystal structure (space group C2/c, a = 21.146(2) Å,...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.