Characteristics, Chemical Speciation and Health Risk Assessment of Heavy Metals in Paddy Soil and Rice around an Abandoned High-Arsenic Coal Mine Area, Southwest China

Abstract

The concentrations of the heavy metals Pb, Cd, Cr, Hg, As, Cu and Zn in soil and locally produced grain (rice) were determined in paddy soil and rice around an abandoned high-arsenic coal mine area of Xingren county, southwest China. The health risk assessment was used to assess the multimedia and multipathway health risks of HM exposure in the study area. The results showed that the concentrations of As, Pb and Cd in soil were all higher than the corresponding limits for HMs in China. In terms of the accumulation and transfer capacity, Cd was more likely to transfer from the roots to rice, and its strong mobility may pose potential risks to local residents. The non-carcinogenic risks and carcinogenic risks of HM exposure in different media and exposure pathways were higher in children than adults. The total non-carcinogenic risks and carcinogenic risks in adults and children were higher than the standard limit values because of the HM exposure through ingesting rice husk. Among the exposure pathways evaluated, the contribution of diet was the largest, and As was the most important heavy metal in terms of the non-carcinogenic risk and carcinogenic risk factors. The total non-carcinogenic risks and carcinogenic risks caused by As in dietary crop (rice) accounted for 52% of the total in both adults and children. In order to maintain the health of residents in the study area, it is necessary to strictly strengthen the monitoring of heavy metal pollution in the study area and find effective soil improvement methods to reduce the health risks caused by heavy metal exposure.

Health and ecological risk of heavy metals in agricultural soils related to Tungsten mining in Southern Jiangxi Province, China

“…The TF values for Cd were above 2 in FJ-S, HL, and CJ-E and above 5 in QL, indicating serious accumulation. This results is coincident with the study of Liu et al (2023) which indicates that the paddy rice has high TF and BAF values (mean:0.99 and 0.91, respectively) of Cd. Yang et al (2021) reached the opposite conclusion when studying the enrichment of Cd in rice in southern karst geological areas.…”

Heavy Metal Pollution Assessment in the Agricultural Soils of Bonao, Dominican Republic

“…The average levels of Fe, Ni, Cu, As, and Pb in the topsoil were higher than the natural background values. This suggests that the amount of these elements may have increased due to human activities such as mining, insecticide use, fertilizer applications, and transportation [6,40]. Because of the lack of official guidelines for healthy concentrations of metals in agricultural soils in the Dominican Republic, the mean concentrations of the different heavy metals were compared to the maximum levels of heavy metals for healthy agricultural soils adopted by the FAO [41] and the normal range of concentrations of heavy metals in agricultural soils introduced by Kabata-Pendias [42].…”

Assessment of Heavy Metal(loid) Pollution and Human Health Risks Associated with a Mineral (Zn, Cu, and Sn Ores) Processing Plant in Yunnan, Southwest China

“…The water was highly contaminated by Cr and Pb [23]. As [24,25], Pb [26], and Cd [27] pose health risks to humans. Therefore, it is particularly important to objectively evaluate the pollution characteristics and ecological risks of HMs at historical sites and identify their migration and enrichment pathways.…”