Characterization, physical properties, and potential industrial applications of high oleic pennycress oil

Winfield, DeMichael D.; Dunn, Robert O.; Winkler-Moser, Jill K.; Cermak, Steven C.; Marks, David M.

doi:10.1016/j.indcrop.2024.118095

Cited by 1 publication

(3 citation statements)

References 19 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The previously unreported data for the dark-colored I-Coco and I-Coco-2EH before charcoal cleaning (both having Gardner color of 17) were also used. These samples are labeled with (17) after the acronym. The CP (D2500) and PP (D97) of I-Coco(17) were −33.3 and −36 • C, while for I-Coco-2EH(17) were −13.0 and −33 • C. Scheme 1.…”

Section: Methodsmentioning

confidence: 99%

“…The saturated fatty acids are the main contributor to the poor low-temperature properties, while unsaturated fatty acids with one or more double bonds are prone to oxidation [13]. The oleic acid with one double bond is the best "compromise" fatty acid, which leads to the interest in high-oleic oils [14][15][16][17]. Nevertheless, even these oils lack sufficient performance for most of the applications.…”

Section: Introductionmentioning

confidence: 99%

“…Still, transesterifications have limited effect on the cold-flow properties and oxidative stability of vegetable oil. Due to this, reacting of the double bonds is often included as part of bio-based lubricant synthesis [5][6][7][15][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30][31][32][33][34]. The bio-based lubricants and related materials are used to some extent in almost every application [5][6][7]24,35,36].…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Cold-Flow Properties of Estolides: The Older (D97 and D2500) versus the Mini-(D5773 and D5949) Methods

Bantchev,

Ngo,

Chen

et al. 2024

Lubricants

Self Cite

View full text Add to dashboard Cite

There is growing research on developing new and sustainable lubricants. Sustainable lubricants with adequate cold-flow properties are of particular interest for many applications. One limitation of the established methods for measuring cold flow properties is the large volume needed to test samples. This makes initial screening of many hard-to-synthesize samples difficult. In the current study, we compared the results of the older, widely accepted ASTM methods D97 (pour point, PP) and D2500 (cloud point, CP) to the newer, smaller-volume, and easier-to-perform methods D5949 and D5773 for bio-based base oils (estolides and iso-estolides). The CP results were in good agreement for less colored samples, but D5773 gave lower values for some darker (Gardner color >8) samples, especially esters. The D5949 showed a tendency to report slightly higher PP, especially for the lower values. Viscosities and densities in a wide temperature range (15 to 120 °C) were also measured. The surface tensions were estimated by a literature group method. Viscosity and density effects can only partially explain the differences in the PP values from the two methods. In conclusion, the newer mini-methods are an acceptable substitution when larger volumes are not accessible, unless the sample is too dark.

show abstract

Section: Methodsmentioning

confidence: 99%