Charge Transfer and Intersystem Crossing in Compact Naphthalenediimide–Phenothiazine Triads: Synthesis and Study of the Photophysical Property with Transient Optical and Electron Paramagnetic Resonance Spectroscopic Methods
Lezhang Liu,
Xi Liu,
Ivan Kurganskii
et al.
Abstract:In order to obtain a long-lived charge separation (CS) state in compact electron donor−acceptor molecular systems, we prepared a series of naphthalenediimide (NDI)−phenothiazine (PTZ) triads, with phenylene as the linker between the donor and acceptor. Conformation restriction is imposed to control the mutual orientation of the NDI and PTZ units by attaching methyl groups on the phenylene linker to tune the electronic coupling between the donor and the acceptor. Moreover, the PTZ moiety was oxidized to sulfoxi… Show more
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