ChemInform Abstract: (2 + 4) Cycloaddition Reactions of Perfluoroazomethines.

Abstract

083ChemInform Abstract The perfluoroazomethines (I) react with cyclopentadiene (II) to give exo/endo mixtures of the azabicycloheptenes (III). Chlorine, bromine, or hexafluorodimethylnitroxyl combine with the double bond of (III) toyield the adducts (IV). (1H-, 19F-NMR-data).