ChemInform
 2012
DOI: 10.1002/chin.201227042
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ChemInform Abstract: A Copper‐Based Catalytic System for Carboxylation of Terminal Alkynes: Synthesis of Alkyl 2‐Alkynoates.

Kiyofumi Inamoto
1
,
Narumi Asano
2
,
Koji Kobayashi
3
et al.

Abstract: Under ambient conditions, aromatic, heteroaromatic, and aliphatic alkynes undergo the CuI/PEt3 catalyzed carboxylation with CO2 and alkyl bromides or iodides to give the title esters.

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