ChemInform Abstract: A New and More Powerfully Activating Diamine for Practical and Scalable Enantioselective Aldehyde Crotylsilylation.

Abstract

A New and More Powerfully Activating Diamine for Practical and Scalable Enantioselective Aldehyde Crotylsilylation. -A convenient one-pot protocol employing an optically active diaminophenol activator ligand for the diastereo-and enantioselective allylation and crotylation of aldehydes is developed. -(SUEN, L. M.; STEIGERWALD, M. L.; LEIGHTON*, J. L.; Chem. Sci. 4 (2013) 6, 2413-2417, http://dx.doi.org/10.1039/c3sc50714a ; Dep. Chem., Columbia Univ., New York, NY 10027, USA; Eng.) -Mais 46-034