ChemInform Abstract: A Route to 1‐Alkenylphosphine Derivatives via the Zr‐Catalyzed Reaction of 1‐Alkynylphosphines with Triethylaluminum.

Abstract

A Route to 1-Alkenylphosphine Derivatives via the Zr-Catalyzed Reaction of 1-Alkynylphosphines with Triethylaluminum. -The title reaction under conditions A) produces organoaluminum intermediates (III). They are elaborated to different interesting derivatives including the phosphole (VIII) as a potential bidentate organophosphorus ligand. -(RAMAZANOV*, I. R.; KADIKOVA, R. N.; SAITOVA, Z. R.; DZHEMILEV, U. M.; Asian J.