ChemInform Abstract: A Versatile Difluorovinylation Method: Cross‐Coupling Reactions of the 2,2‐Difluorovinylzinc—TMEDA Complex with Alkenyl, Alkynyl, Allyl, and Benzyl Halides.

Abstract

A Versatile Difluorovinylation Method: Cross-Coupling Reactions of the 2,2-Difluorovinylzinc-TMEDA Complex with Alkenyl, Alkynyl, Allyl, and Benzyl Halides. -Title zinc complex (II) is synthesized and applied to transition metal-catalyzed cross-coupling reactions with a wide range of organic halides yielding 2,2-difluorovinyl compounds. Complex (II) is storable and can easily be handled. -(ICHITSUKA, T.; TAKANOHASHI, T.; FUJITA, T.; ICHIKAWA*, J.; J. Fluorine Chem. 170 (2015) 29-37, http://dx.