ChemInform Abstract: An Efficient Synthetic Method of Aliphatic Selenoamides via Selenoketene Intermediates.

Abstract

An Efficient Synthetic Method of Aliphatic Selenoamides via Selenoketene Intermediates.-Selenoamides are efficiently synthesized by treatment of terminal acetylenes or the bromopropene (XIII) according to A) followed by trapping the resulting selenoketene intermediate with amines. -(MURAI, T.; EZAKA, T.; NIWA, N.; KANDA, T.; KATO, S.; Synlett (1996) 9, 865-866; Dep. Chem., Fac. Eng., Gifu Univ., Yanagido, Gifu 501-11, Japan; EN)