ChemInform Abstract: AN ESR STUDY OF N‐ALKOXYSULFONAMIDYL RADICALS

Abstract

An ESR Study of N‐Alkoxysulfonamidyl Radicals.

Geminal oxygen–nitrogen–halogen systems.N-Halohydroxylamine derivatives

“…1 Photolysis of solutions of N-bromo-N-alkoxysulfonamides 47 in CFCl 3 or in a mixture of CFCl 3 with CH 2 Cl 2 at 730 to 760 8C is accompanied by the generation of the corresponding N-alkoxysulfonamidyl radicals, which have been detected by EPR spectroscopy. 84,85 R=F, Cl, Br, C2F5O, C3F7OCF(CF3)CF2O; R=CF3, C5F11, SF5, FCO.…”