ChemInform Abstract: Apparent Endo‐Mode Cyclic Carbopalladation with Inversion of Alkene Configuration via Exo‐Mode Cyclization‐Cyclopropanation‐Rearrangement.

Abstract

1993 ring closure reactions ring closure reactions O 0130 -099Apparent Endo-Mode Cyclic Carbopalladation with Inversion of Alkene Configuration via Exo-Mode Cyclization-Cyclopropanation-Rearrangement.-Mechanisms of the cyclization of some dialkenes via carbopalladation are discussed by NMR spectroscopic analysis in terms of experimental results and literature informations.-(OWCZARCZYK, Z.; LAMATY, F.; VAWTER, E. J.; NEGISHI, E.; J.